Lenny, when i want to paint chrome,i will sandblast the item it doesnt remove the chrome unless flaking off. but it does rough it up so the paint will stick.
if you're going black on your side pipes i recommend using spray paint from Southern Coatings. it is designed for high heat such as b-b-que grills.once on it will cure as you run the car,and once cured does real well at resisting chemicals and rust.
i ususally buy mine at lowe's...hope this is helpful
Robin....grillin' and chillin'
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